{"id":675,"date":"2019-03-11T08:08:44","date_gmt":"2019-03-11T11:08:44","guid":{"rendered":"http:\/\/www.lme.pcc.usp.br\/?p=675"},"modified":"2019-10-04T14:32:09","modified_gmt":"2019-10-04T17:32:09","slug":"using-isothermal-calorimetry-x-ray-diffraction-thermogravimetry-and-ftir-to-monitor-the-hydration-reaction-of-portland-cements-associated-with-red-mud-as-a-supplementary-material","status":"publish","type":"post","link":"https:\/\/www.lme.pcc.usp.br\/en\/using-isothermal-calorimetry-x-ray-diffraction-thermogravimetry-and-ftir-to-monitor-the-hydration-reaction-of-portland-cements-associated-with-red-mud-as-a-supplementary-material\/","title":{"rendered":"Using isothermal calorimetry, X-Ray diffraction, thermogravimetry and FTIR to monitor the hydration reaction of Portland cements associated with red mud as a supplementary material"},"content":{"rendered":"<p>&nbsp;<\/p>\r\n\r\n<p>&nbsp;<\/p><!-- \/wp:paragraph -->\r\n<p>&nbsp;<\/p>\r\n<!-- wp:paragraph -->\r\n<p>&nbsp;<\/p><!-- wp:paragraph -->\r\n<p>Authors: Romano, Roberto Cesar de O.; Bernardo, Heitor M.; Maciel, Marcel H.; Pileggi Rafael G.; Cincotto, Maria A.<\/p>\r\n<!-- \/wp:paragraph -->\r\n<p>&nbsp;<\/p>\r\n<!-- wp:paragraph -->\r\n<p>Journal: Journal of Thermal Analisys and Calorimetry <a href=\"https:\/\/doi.org\/10.1007\/s10973-019-08095-x\">(doi)<\/a><\/p>\r\n<!-- \/wp:paragraph -->\r\n<p>&nbsp;<\/p>\r\n<!-- wp:paragraph -->\r\n<p>Available online: 2 de Mar\u00e7o de 2019<\/p>\r\n<!-- \/wp:paragraph -->\r\n<p>&nbsp;<\/p>\r\n<!-- wp:paragraph -->\r\n<p><strong>Abstract<\/strong><\/p>\r\n<!-- \/wp:paragraph -->\r\n<p>&nbsp;<\/p>\r\n<!-- wp:paragraph -->\r\n<p>This study is part of a global project to find some large-scale application for red mud. A previous work confirmed that the<br \/>use of RM as partial substitution for cement can affect its rheological properties; however, it is possible to produce<br \/>cementitious materials without lose mechanical performances at harden state. The main goal of the work was to assess the<br \/>impact of red mud (RM) as replacement of different Brazilian Portland cements by monitoring the formation of hydrated<br \/>products over time, by thermogravimetry, X-ray diffraction and FTIR. Results show that the presence of RM increases the<br \/>induction period, the gypsum and portlandite consumption as well as the amount of ettringite and monosulfoaluminate<br \/>produced. The formation of sodium silicoaluminate hydrate (NASH) was also observed, regardless the kind of cement, as a<br \/>result of the reaction with aluminates and silicates from the binder.<\/p>\r\n<!-- \/wp:paragraph -->\r\n<p>&nbsp;<\/p>\r\n<!-- wp:paragraph \/-->\r\n<p>&nbsp;<\/p>\r\n<!-- wp:paragraph -->\r\n<p>&nbsp;<\/p>\r\n<!-- wp:paragraph -->\r\n<p>&nbsp;<\/p><!-- \/wp:post-content --><!-- \/wp:paragraph --><!-- wp:post-content --><!-- wp:paragraph -->\r\n<p>Authors: Romano, Roberto Cesar de O.; Bernardo, Heitor M.; Maciel, Marcel H.; Pileggi Rafael G.; Cincotto, Maria A.<\/p>\r\n<!-- \/wp:paragraph -->\r\n<p>&nbsp;<\/p>\r\n<!-- wp:paragraph -->\r\n<p>Journal: Journal of Thermal Analisys and Calorimetry <a href=\"https:\/\/doi.org\/10.1007\/s10973-019-08095-x\">(doi)<\/a><\/p>\r\n<!-- \/wp:paragraph -->\r\n<p>&nbsp;<\/p>\r\n<!-- wp:paragraph -->\r\n<p>Available online: 2 de Mar\u00e7o de 2019<\/p>\r\n<!-- \/wp:paragraph -->\r\n<p>&nbsp;<\/p>\r\n<!-- wp:paragraph -->\r\n<p><strong>Abstract<\/strong><\/p>\r\n<!-- \/wp:paragraph -->\r\n<p>&nbsp;<\/p>\r\n<!-- wp:paragraph -->\r\n<p>This study is part of a global project to find some large-scale application for red mud. A previous work confirmed that the<br \/>use of RM as partial substitution for cement can affect its rheological properties; however, it is possible to produce<br \/>cementitious materials without lose mechanical performances at harden state. The main goal of the work was to assess the<br \/>impact of red mud (RM) as replacement of different Brazilian Portland cements by monitoring the formation of hydrated<br \/>products over time, by thermogravimetry, X-ray diffraction and FTIR. Results show that the presence of RM increases the<br \/>induction period, the gypsum and portlandite consumption as well as the amount of ettringite and monosulfoaluminate<br \/>produced. The formation of sodium silicoaluminate hydrate (NASH) was also observed, regardless the kind of cement, as a<br \/>result of the reaction with aluminates and silicates from the binder.<\/p>\r\n<!-- \/wp:paragraph -->\r\n<p>&nbsp;<\/p>\r\n<!-- wp:paragraph --><!-- \/wp:paragraph -->\r\n<p>&nbsp;<\/p>\r\n<!-- wp:paragraph -->\r\n<p>&nbsp;<\/p>\r\n<!-- wp:paragraph -->\r\n<p>&nbsp;<\/p><!-- \/wp:post-content -->","protected":false},"excerpt":{"rendered":"<p>&nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; Authors: Romano, Roberto Cesar de O.; Bernardo, Heitor M.; Maciel, Marcel H.; Pileggi&#46;&#46;&#46;<\/p>\n","protected":false},"author":714,"featured_media":603,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":"","_links_to":"","_links_to_target":""},"categories":[9],"tags":[93,48,70],"class_list":["post-675","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-publicacoes","tag-hydration-reaction","tag-portland-cement","tag-red-mud"],"_links":{"self":[{"href":"https:\/\/www.lme.pcc.usp.br\/en\/wp-json\/wp\/v2\/posts\/675","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.lme.pcc.usp.br\/en\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.lme.pcc.usp.br\/en\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.lme.pcc.usp.br\/en\/wp-json\/wp\/v2\/users\/714"}],"replies":[{"embeddable":true,"href":"https:\/\/www.lme.pcc.usp.br\/en\/wp-json\/wp\/v2\/comments?post=675"}],"version-history":[{"count":4,"href":"https:\/\/www.lme.pcc.usp.br\/en\/wp-json\/wp\/v2\/posts\/675\/revisions"}],"predecessor-version":[{"id":725,"href":"https:\/\/www.lme.pcc.usp.br\/en\/wp-json\/wp\/v2\/posts\/675\/revisions\/725"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.lme.pcc.usp.br\/en\/wp-json\/wp\/v2\/media\/603"}],"wp:attachment":[{"href":"https:\/\/www.lme.pcc.usp.br\/en\/wp-json\/wp\/v2\/media?parent=675"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.lme.pcc.usp.br\/en\/wp-json\/wp\/v2\/categories?post=675"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.lme.pcc.usp.br\/en\/wp-json\/wp\/v2\/tags?post=675"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}